Exhaust Gas Cleaning Systems & Marine Scrubbers

Marine & Offshore — EGCS Systems

Spray Nozzles for
Exhaust Gas Cleaning Systems & Marine Scrubbers

EGCS washwater injection nozzles operate in conditions that make most industrial spray hardware the wrong choice from the start. Hot exhaust gas at 200–250°C acidified to pH 2–3 by dissolved sulfur dioxide from HSFO combustion creates an environment where 316L stainless steel pits through its full wall thickness within a single dry-dock cycle. Correct nozzle material selection — Duplex 1.4462, Super Duplex 2507, or Silicon Carbide — is not a performance upgrade. It is the difference between a scrubber that achieves MARPOL Annex VI compliance on every voyage and one that fails before the next Port State Control inspection.

pH 2–3 EGCS washwater acidity from dissolved SO₂ — the condition that destroys 316L SS and demands Duplex or SiC
200–250°C Exhaust gas inlet temperature before scrubbing — nozzle body and orifice must maintain dimensional stability at this temperature
PREN 35–38 vs. 24–26 for 316L Duplex 1.4462 Pitting Resistance Equivalent Number — quantifies the corrosion resistance advantage in chloride-acid service
IMO 2020 0.5% global sulfur cap — the regulation that made EGCS scrubbers the primary compliance pathway for HSFO-burning vessels
ISO 9001 NozzlePro manufacturing certification — consistent orifice dimensions and material grades across production orders
What spray nozzles are used in marine EGCS scrubbers?

Marine exhaust gas cleaning system (EGCS) scrubbers use spray nozzles to inject washwater — either seawater in open-loop systems or recirculated alkaline solution in closed-loop systems — into the exhaust gas stream. The washwater contacts the sulfur dioxide in the exhaust, absorbs it, and carries the resulting sulfurous and sulfuric acid out of the gas phase and into the washwater discharge stream. The nozzles that accomplish this operate continuously in a corrosive, high-temperature environment that is among the most demanding in any industrial spray application.

The correct nozzle specification for EGCS service depends on the position within the scrubber (primary inlet spray tower vs. venturi throat vs. secondary polishing stages), the exhaust gas temperature at that position, the pH of the washwater at that position, and whether the system is open-loop (seawater), closed-loop (alkaline solution), or hybrid. No single nozzle type or material grade is correct for all positions in an EGCS installation — this page covers the engineering basis for position-by-position specification.

System Architecture

Open-Loop vs. Closed-Loop Scrubbers: Different Chemistry, Different Nozzle Demands

The fundamental difference between open-loop and closed-loop EGCS systems is what the washwater contains — and that difference directly determines nozzle material grade, orifice geometry, and maintenance interval.

Open-Loop Systems

Seawater washwater — unrestricted ocean operation
Seawater enters the scrubber directly from the sea chest, passes through the spray nozzles into the exhaust gas stream, absorbs SO₂, and is discharged overboard after treatment — the ocean's natural alkalinity (typically pH 8.1–8.3) provides the absorption chemistry, eliminating the need for chemical dosing
Nozzle challenge: seawater contains 35,000 ppm dissolved chloride — at the nozzle inlet where fresh seawater meets the hot, acidified exhaust atmosphere, the nozzle body exterior experiences a combined chloride-acid environment while the interior handles cool raw seawater; this dual-surface attack requires chloride pitting resistance across both surfaces
Prohibited in many ports and emission control areas (ECAs) due to washwater discharge regulations — vessels operating in the Baltic, North Sea, and many port approaches must switch to closed-loop mode or use distillate fuel when open-loop discharge is restricted
Nozzle scale and biological fouling is a secondary concern in open-loop service — seawater carries marine organisms and calcium/magnesium scale precursors that can partially block small orifices; specify large free-passage orifice designs for open-loop scrubber positions
Material minimum: Duplex 1.4462 throughout — 316L SS is not adequate for the combined seawater chloride and exhaust gas acid exposure at elevated temperatures present in the primary spray zone

Closed-Loop Systems

Recirculated alkaline washwater — ECA and port operation
Recirculated washwater is dosed with sodium hydroxide (NaOH) to maintain alkalinity for continued SO₂ absorption — the same washwater passes through the nozzles, contacts the exhaust gas, absorbs SO₂, and returns to the recirculation sump for treatment and re-dosing; a bleed-and-feed arrangement manages the buildup of dissolved sulfate salts in the recirculating loop
Nozzle challenge: recirculated washwater progressively accumulates dissolved sulfate (from SO₂ absorption), chloride (from seawater bleed-in), and suspended particulate matter from the exhaust gas; the recirculating liquid becomes more aggressive over time and carries abrasive fine particulate that erodes small-orifice nozzles from the inside
Higher dissolved solids in closed-loop washwater increase the risk of nozzle orifice scale deposition — specify large free-passage designs and plan for more frequent orifice inspection than open-loop seawater service
NaOH dosing creates an alkali-then-acid cycling environment at the nozzle: the nozzle body interior sees alkaline solution, but the nozzle exterior and the spray zone immediately downstream see the acidic exhaust atmosphere; the nozzle material must be resistant to both
Material minimum: Duplex 1.4462 — same as open-loop; specify Super Duplex 2507 at the primary inlet spray position in closed-loop systems where the recirculating washwater pH has dropped below 4 at the nozzle injection point
Position-by-Position Specification

Three Spray Positions, Three Different Engineering Problems

A marine scrubber is not a single-position spray application. The temperature, pH, gas velocity, and water quality at the primary inlet spray tower, the venturi throat, and the secondary polishing stages are all different — and the nozzle specification at each position must be derived from the conditions at that position, not from a single system-wide selection.

Position 01

Primary Inlet Spray Tower

Highest temperature — highest acid exposure

The primary inlet spray tower is where exhaust gas enters the scrubber at its highest temperature — typically 200–280°C for a large two-stroke marine diesel on heavy fuel oil. The first rows of washwater injection nozzles in this zone experience the full incoming exhaust temperature on the downstream face while injecting washwater at near-ambient temperature. This creates a thermal gradient across the nozzle body that, combined with the highly acidic, chloride-bearing exhaust atmosphere, creates the most demanding material environment in the entire EGCS installation.

The washwater at this position is also most effective at SO₂ absorption because the driving force for gas absorption into liquid is highest when the washwater is fresh (lowest dissolved SO₂ content) and the gas is hottest. Getting the droplet size right at this position — fine enough to maximize the gas-liquid contact area but coarse enough to fall against the upward draft of incoming exhaust gas — has the largest impact on overall scrubber efficiency of any position in the system.

Hollow-cone or full-cone spiral nozzles producing Dv50 of 300–600 µm — large enough to fall against the incoming gas draft (typically 2–5 m/s upward velocity in the primary spray zone), fine enough to provide adequate gas-liquid contact area for SO₂ absorption
Super Duplex 2507 or Silicon Carbide ceramic body as the correct specification for this position — Duplex 1.4462 is adequate for most service but the primary inlet position's combination of 200°C+ temperature, pH 2–3, and high gas-phase chloride loading pushes into the service limit of standard Duplex; SiC ceramic nozzle bodies provide effectively unlimited corrosion resistance at this position
Large free-passage orifice — seawater and recirculated closed-loop washwater both carry particulate; the primary inlet nozzle receives the highest-temperature, lowest-viscosity washwater that provides the least barrier against particulate ingestion; specify minimum 15–20 mm free passage at this position
Multiple staggered spray rings at defined elevations — the primary spray tower typically uses 2–4 spray rings at 1–2 m spacing, each covering the full tower cross-section; the ring closest to the exhaust gas inlet receives the most extreme conditions and should be specified at the highest material grade in the installation
Super Duplex 2507 or SiC Dv50 300–600 µm Hollow-Cone or Full-Cone Spiral
Position 02

Venturi Scrubber Throat

Highest gas velocity — maximum abrasion

Venturi scrubber designs accelerate the exhaust gas through a constricted throat section, typically achieving gas velocities of 40–80 m/s at the throat. At these velocities, the exhaust gas carries fine particulate matter from incomplete combustion at sufficient kinetic energy to cause direct erosion of nozzle bodies and orifice edges — the same dual-surface abrasion mechanism described for blast furnace gas scrubbers, but now combined with seawater chloride and acid exhaust gas chemistry that accelerates the corrosion component of the corrosion-erosion synergy.

Silicon Carbide (SiC) orifice inserts in a Duplex 1.4462 or Super Duplex body are the correct specification at the venturi throat — SiC provides 10–20× the erosion resistance of Duplex stainless at 40–80 m/s gas velocity; the metallic body handles the structural load and connection requirements while the SiC insert protects the critical orifice geometry
Venturi throat nozzle spray angle must be calculated from the throat geometry — the water injection at the venturi throat must produce droplets that are immediately atomized and dispersed by the high-velocity gas stream; the nozzle spray direction is typically perpendicular to the gas flow or at a calculated impingement angle to maximize droplet-gas contact in the short residence time of the venturi throat zone
Inspect venturi throat nozzles at every dry-dock interval — the erosion rate at this position is the highest in the scrubber; orifice wear beyond 10% of original diameter shifts the droplet size distribution coarser and reduces scrubber efficiency; the enlarged orifice delivers more flow at the same supply pressure, which can mask the performance degradation in flow monitoring systems
SiC inserts mandatory Duplex or S.Duplex body Inspect every dry-dock
Position 03

Secondary Polishing & Mist Eliminator Wash

Lower temperature — fine droplet entrainment prevention

After the primary scrubbing stage, the partially cleaned exhaust gas passes through secondary spray stages and a mist eliminator section. The secondary spray stages continue SO₂ absorption at lower gas temperatures (typically 40–80°C at this point) and lower acid concentrations. The mist eliminator wash nozzles periodically flush the mist eliminator panels to prevent salt and acid deposits from building up on the surface and restricting gas flow. These positions operate in a much less aggressive environment than the primary inlet — but they still require corrosion-resistant materials because the exhaust gas is still acidic and chloride-bearing.

Duplex 1.4462 is adequate for secondary polishing stage nozzles where temperature has fallen below 100°C and acid concentration has been reduced by the primary stage; 316L SS is not recommended even at this position — the combined seawater chloride and residual exhaust gas acid still creates conditions above 316L SS's reliable pitting resistance threshold in continuous service
Mist eliminator wash nozzles: full-cone, Duplex 1.4462, low pressure (1–3 bar) — the function is periodic flushing of accumulated deposits, not primary SO₂ absorption; the spray angle and flow rate are sized to thoroughly wet the mist eliminator panel area during each wash cycle without creating excessive water loading that reduces gas-phase efficiency during normal operation
Secondary stage nozzle scale monitoring — at the cooler temperatures in the secondary zone, dissolved calcium and magnesium from the washwater precipitate more readily; inspect for orifice scale buildup at each planned maintenance interval and acid-clean if flow rate deviation exceeds ±10% of rated output
Duplex 1.4462 — adequate Full-Cone, 1–3 bar Monitor for scale
Position 04

Scrubber Sump & Internal Washing

Removing soot and sulfate deposits between voyages

During operation, carbonaceous soot and amorphous sulfate deposits accumulate on the internal surfaces of the scrubber tower, on the spray ring manifolds, and on the mist eliminator panels. These deposits reduce gas-liquid contact efficiency, restrict gas flow through the scrubber, and — if allowed to build up into thick layers — can detach as large slugs that block individual nozzle orifices. Internal washing of the scrubber tower between voyages or at scheduled maintenance intervals is necessary to maintain design scrubbing efficiency throughout the vessel's operational life.

High-impact flat-fan nozzles or solid-stream nozzles on traversing manifolds provide the mechanical impact force needed to dislodge thick soot and sulfate deposits from internal scrubber tower surfaces — the same principle as industrial soot washing but in a confined cylindrical geometry with restricted access
Duplex 1.4462 for all internal wash nozzles — the scrubber internal environment retains acidity even after gas flow has stopped; washing a shut-down scrubber with fresh or slightly alkaline water contacts all the acid deposits on the internal surfaces, creating a variable-pH environment; Duplex handles this range reliably
Document wash water pH discharge — IMO MEPC guidelines require that washwater discharge from scrubber cleaning operations meets pH requirements before overboard discharge; coordinate the internal wash cycle with the vessel's EGCS washwater management plan
High-Impact Flat-Fan or Solid-Stream Duplex 1.4462 Monitor pH discharge
Deep Dive — Spray Engineering

Droplet Size Optimization for SO₂ Absorption: Balancing Contact Area Against Draft Pressure Drop

The droplet size distribution produced by EGCS washwater injection nozzles is the primary determinant of scrubbing efficiency at any given washwater flow rate. Getting it wrong in either direction — too fine, or too coarse — costs money in fuel use, capital in oversized equipment, or compliance risk from under-performance.

Why Finer Is Not Always Better for Marine Scrubber Droplets

SO₂ absorption from gas phase into liquid phase is governed by mass transfer theory — the rate of absorption is proportional to the total gas-liquid interfacial area, which is proportional to the total droplet surface area per unit volume of scrubber. For a given washwater flow rate, smaller droplets produce more total surface area than larger droplets (surface area scales as 1/d for a given volume). This creates a strong engineering incentive to produce the finest possible droplets to maximize scrubbing efficiency.

However, EGCS scrubbers operate with an upward-flowing exhaust gas stream that carries the droplets with it if they are fine enough to be entrained. The terminal settling velocity of a water droplet in air scales with the square of the droplet diameter — a 100 µm droplet has a terminal velocity of approximately 0.25 m/s, while a 500 µm droplet settles at approximately 2.5 m/s. In a scrubber tower where the upward gas velocity is 2–4 m/s, droplets below approximately 300–400 µm will be carried upward by the gas stream rather than falling downward to the sump — they either re-entrain into the cleaned gas and escape through the exhaust stack, or they load the mist eliminator section, increasing pressure drop and reducing the available gas throughput.

The Pressure Drop Penalty of Over-Fine Atomization

In a marine EGCS installation, the scrubber creates a pressure drop in the exhaust gas path that the engine must overcome — this additional back-pressure is the direct energy cost of the scrubbing operation. Fine atomization that creates excessive mist eliminator loading raises the pressure drop across the scrubber beyond the design value. On a large two-stroke marine diesel, each additional 10 mbar of exhaust back-pressure corresponds to approximately 0.3–0.5% increase in specific fuel oil consumption. For a 12,000 kW main engine operating at sea for 5,000 hours per year at $600/tonne HSFO cost, an additional 0.4% fuel consumption from excess back-pressure costs approximately $15,000–25,000 per year — more than the cost of re-specifying the nozzle array. Contact NozzlePro with your scrubber tower diameter, exhaust gas flow rate, and design gas velocity to receive a droplet size recommendation specific to your system.

The 316L Pitting Failure Mechanism — Why Standard Stainless Is Wrong for EGCS

316L austenitic stainless steel achieves its corrosion resistance through a passive chromium oxide film on its surface. In clean seawater at ambient temperature, this passive film is stable and provides adequate protection against general corrosion. In the EGCS washwater environment — chloride-bearing water at elevated temperature, in contact with acidified exhaust gas at pH 2–3 — the passive film is attacked by two simultaneous mechanisms that work synergistically.

Chloride ions destabilize the passive film at surface defects, initiating pitting corrosion at the defect sites. The acid environment (pH 2–3) prevents the passive film from re-forming over active pit sites — once a pit is initiated, the local pit chemistry becomes increasingly acidic (FeCl₃ hydrolysis), which further prevents repassivation and accelerates the pit growth rate. This autocatalytic mechanism is what causes 316L SS EGCS nozzles to fail through pitting in months of service rather than years — the pits grow progressively until they penetrate through the nozzle wall or cause mechanical failure of the orifice edge.

Duplex 1.4462's higher pitting resistance — quantified by the PREN formula (PREN = %Cr + 3.3×%Mo + 16×%N) — reflects a passive film that is more resistant to chloride-induced depassivation. At PREN 35–38, Duplex 1.4462 maintains passive film stability at chloride concentrations and temperatures where 316L SS (PREN 24–26) has already entered active pitting. For the primary inlet spray position where temperature and acid loading are highest, Super Duplex 2507 (PREN above 40) provides the additional margin required for reliable long-term service between dry-dock intervals.

316L SS Failure Is Not Gradual — It Accelerates

Once pitting initiates in a 316L SS EGCS nozzle, the autocatalytic pit growth mechanism means the failure rate accelerates rather than remaining constant. A nozzle that shows no visible corrosion after six months may show through-wall pitting within the following three months because the local pit chemistry has become self-sustaining. Port State Control inspections that find EGCS nozzle failures can result in operational restrictions that are far more expensive than the cost of correct Duplex specification at initial installation. The incremental cost between 316L SS and Duplex 1.4462 EGCS nozzles is recoverable within a single avoided repair incident.

Material Selection Guide

EGCS Nozzle Material by Scrubber Position

Contact NozzlePro with your scrubber OEM, tower geometry, exhaust gas temperature profile, and washwater chemistry. Position-specific material selection is essential — a single material grade across the entire scrubber is either over-specified at some positions or under-specified at others.

Scrubber Position Temp. Range pH at Position Recommended Material Key Constraint Replace At
Primary inlet spray rings — closest to exhaust gas entry 200–280°C pH 2–3 Super Duplex 2507 body or SiC ceramic Highest temp + highest acid loading — Duplex 1.4462 at its service limit; SiC preferred for infinite corrosion resistance Inspect every dry-dock; replace at any sign of pitting or orifice distortion
Primary spray rings — upper rows (gas partially cooled) 120–200°C pH 2.5–4 Duplex 1.4462 or Super Duplex Still within corrosion-acceleration range for 316L SS; Duplex 1.4462 provides adequate service; upgrade to Super Duplex if gas temperature stays above 150°C at this position Inspect every 12 months; replace at 10% flow deviation
Venturi throat injection 150–250°C pH 2–3 Duplex or Super Duplex body + SiC inserts 40–80 m/s gas velocity causes rapid abrasion of metallic orifices — SiC inserts mandatory at venturi throat regardless of corrosion grade Inspect every dry-dock; measure orifice diameter; replace at >10% enlargement
Secondary polishing spray stages 40–80°C pH 4–6 Duplex 1.4462 Adequate corrosion resistance at lower temperature and pH; scale monitoring required; do not specify 316L SS even at this position Inspect every 12 months; acid-clean if scale detected
Mist eliminator wash nozzles 40–80°C pH 5–7 Duplex 1.4462 Low-pressure periodic flushing — moderate chemical environment; full-cone pattern for panel coverage; 1–3 bar supply pressure Inspect every 12 months
Scrubber internal soot wash Ambient–60°C Variable pH Duplex 1.4462 Variable pH during washing as acid deposits dissolve; high-impact flat-fan or solid-stream; Duplex handles the full range Inspect annually
Technical Quick Reference

EGCS Scrubber Nozzle Specification at a Glance

NozzlePro Marine EGCS — Engineering Spec Reference

Key Parameters for EGCS Washwater Injection Nozzles

Primary Inlet — Open-Loop (Seawater) Super Duplex 2507 or SiC body — pH 2–3 at 200–280°C — Hollow-cone or full-cone spiral — Dv50 300–600 µm — 15–20 mm min. free passage — PREN >40 required
Primary Inlet — Closed-Loop (NaOH solution) Super Duplex 2507 — Combined alkali interior / acid exterior environment — Same droplet size and free passage requirements — Inspect for scale at planned maintenance intervals
Venturi Throat (all system types) SiC orifice inserts in Duplex 1.4462 or Super Duplex body — 40–80 m/s gas velocity — erosion-dominant failure mode — inspect orifice diameter every dry-dock
Secondary / Polishing Stages Duplex EN 1.4462 / UNS S31803 — 40–80°C — pH 4–6 — Full-cone or hollow-cone — Standard free-passage — 12-month inspection interval
Material PREN Values for Reference 316L SS: PREN 24–26 (not suitable for EGCS primary positions) — Duplex 1.4462: PREN 35–38 — Super Duplex 2507: PREN >40 — SiC ceramic: corrosion-immune in acidic service below pH 0
Droplet Size Guidance (spray tower) Dv50 300–600 µm for primary spray tower — must exceed gas terminal velocity (2–4 m/s tower velocity → requires droplets above 350–400 µm) — finer droplets overload mist eliminator and increase back-pressure

EGCS-Grade Materials Supplied by NozzlePro

All nozzles manufactured under ISO 9001. Material grade documentation available on request. Customers are responsible for classification society submission using NozzlePro-supplied hardware.

Duplex EN 1.4462 / UNS S31803 (PREN 35–38) Super Duplex 2507 / 1.4501 (PREN >40) Silicon Carbide (SiC) ceramic bodies & inserts 316L SS (secondary & ambient-temp positions) PTFE seals (high-temp acid service) ISO 9001 Certified Manufacturing
Marine Hub

EGCS Nozzle Failures Are Operational Disruptions, Not Maintenance Events.

A scrubber that cannot achieve washwater pH targets because its primary inlet nozzles have pitted through fails to demonstrate MARPOL Annex VI compliance at the next Port State Control inspection. Specify Duplex or SiC from installation — not after the first failure. Contact NozzlePro with your scrubber OEM, exhaust gas temperature profile, and washwater chemistry.